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The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...
Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Water splitting using solar radiation has not been commercialized.
To account for the internal energy of the open system, this requires energy transfer terms in addition to those for heat and work. It also leads to the idea of the chemical potential . A wall selectively permeable only to a pure substance can put the system in diffusive contact with a reservoir of that pure substance in the surroundings.
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
An endothermic process is a chemical or physical process that absorbs heat from its surroundings. [1] In terms of thermodynamics, it is a thermodynamic process with an increase in the enthalpy H (or internal energy U) of the system. [2] In an endothermic process, the heat that a system absorbs is thermal energy transfer into the
The system is particle-transfer-insulated from its environment by a boundary that is impermeable to particles, but permissive of transfers of energy as work or heat. These processes are the ones by which thermodynamic work and heat are defined, and for them, the system is said to be closed .
The terms sensible heat and latent heat refer to energy transferred between a body and its surroundings, defined by the occurrence or non-occurrence of temperature change; they depend on the properties of the body. Sensible heat is sensed or felt in a process as a change in the body's temperature.
A heat engine is a system that performs the conversion of a flow of thermal energy (heat) to mechanical energy to perform mechanical work. [ 32 ] [ 33 ] A thermocouple is a temperature-measuring device and a widely used type of temperature sensor for measurement and control, and can also be used to convert heat into electric power.