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A open-chain form of glucose makes up less than 0.02% of the glucose molecules in an aqueous solution at equilibrium. [58] The rest is one of two cyclic hemiacetal forms. In its open-chain form, the glucose molecule has an open (as opposed to cyclic) unbranched backbone of six carbon atoms, where C-1 is part of an aldehyde group H(C=O)−.
For many monosaccharides (including glucose), the cyclic forms predominate, in the solid state and in solutions, and therefore the same name commonly is used for the open- and closed-chain isomers. Thus, for example, the term "glucose" may signify glucofuranose, glucopyranose, the open-chain form, or a mixture of the three.
Fructose (/ ˈ f r ʌ k t oʊ s,-oʊ z /), or fruit sugar, is a ketonic simple sugar found in many plants, where it is often bonded to glucose to form the disaccharide sucrose.It is one of the three dietary monosaccharides, along with glucose and galactose, that are absorbed by the gut directly into the blood of the portal vein during digestion.
In 1897, an unfermentable product obtained by treatment of fructose with bases, in particular lead(II) hydroxide, was given the name glutose, a portmanteau of glucose and fructose, and was claimed to be a 3-ketohexose. [12] [13] However, subsequent studies showed that the substance was a mixture of various other compounds. [13] [14]
Its monosaccharides: glucose and fructose; Their ring types: glucose is a pyranose and fructose is a furanose; How they are linked together: the oxygen on carbon number 1 (C1) of α-D-glucose is linked to the C2 of D-fructose. The -oside suffix indicates that the anomeric carbon of both monosaccharides participates in the glycosidic bond.
This includes common monosaccharides like galactose, glucose, glyceraldehyde, fructose, ribose, and xylose. Many disaccharides, like cellobiose, lactose, and maltose, also have a reducing form, as one of the two units may have an open-chain form with an aldehyde group. [6]
High fructose corn syrup (HFCS) [1] – made from corn starch, containing from 55% fructose [3] to 90% fructose. High maltose corn syrup – mainly maltose, not as sweet as high fructose corn syrup; Honey [1] – consists of fructose and glucose; Inositol [2] – naturally occurring sugar alcohol. Commercial products are purified from corn.
After resorption in the gut, the monosaccharides are transported, through the portal vein, to the liver, where all non-glucose monosacharids (fructose, galactose) are transformed into glucose as well. [4] Glucose (blood sugar) is distributed to cells in the tissues, where it is broken down via cellular respiration, or stored as glycogen.