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Boric acid is a weak acid, with pK a (the pH at which buffering is strongest because the free acid and borate ion are in equal concentrations) of 9.24 in pure water at 25 °C. But apparent p K a is substantially lower in swimming pool or ocean waters because of interactions with various other molecules in solution.
Borax is also easily converted to boric acid and other borates, which have many applications. Its reaction with hydrochloric acid to form boric acid is: Na 2 B 4 O 7 ·10H 2 O + 2 HCl → 4 H 3 BO 3 + 2 NaCl + 5 H 2 O. Borax is sufficiently stable to find use as a primary standard for acid-base titrimetry. [17]: p.316
Disodium octaborate is traded either as a liquid concentrate, or as the tetrahydrate Na 2 B 8 O 13 ·4H 2 O, a white odorless powder. It is used as an insecticide , [ 3 ] [ 4 ] and as a fungicide and algicide , and as a fire retardant ., [ 5 ] [ 6 ] and as a boron micronutrient additive in fertilizers . [ 1 ]
Trimethyl borate is a popular borate ester used in organic synthesis. Borate esters form spontaneously when treated with diols such as sugars and the reaction with mannitol forms the basis of a titrimetric analytical method for boric acid. Metaborate esters show considerable Lewis acidity and can initiate epoxide polymerization reactions. [4]
Sodium borate is a generic name for any salt of sodium with an anion consisting of boron and oxygen, and possibly hydrogen, or any hydrate thereof. It can be seen as a hydrated sodium salt of the appropriate boroxy acid , although the latter may not be a stable compound.
Sodium perborate hydrolyzes (i.e. breaks down in contact with water), producing hydrogen peroxide and borate: [3] (HO) 2 B] 2 (OO) 2) 2− + 2 H 2 O ⇌ 2 [(HO) 2 B(OH)(OOH)] − The resulting hydroperoxide then enter in equilibrium with boric acid B(OH) 3, hydrogen peroxide H 2 O 2, the hydroperoxyl anion − OOH, and the tetrahydroxyborate anion [B(OH) 4] −: [2]
Borate buffered saline (abbreviated BBS) is a buffer used in some biochemical techniques to maintain the pH within a relatively narrow range. Borate buffers have an alkaline buffering capacity in the 8–10 range. Boric acid has a pK a of 9.14 at 25 °C.
Borate anions are largely in the form of the undissociated acid in aqueous solution at physiological pH. No further metabolism occurs in either animals or plants. In animals, boric acid/borate salts are essentially completely absorbed following oral ingestion. Absorption occurs via inhalation, although quantitative data are unavailable.
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