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Pyrophyllite occurs in phyllite and schistose rocks, often associated with kyanite, of which it is an alteration product.It also occurs as hydrothermal deposits. Typical associated minerals include: kyanite, andalusite, topaz, mica and quartz.
The Si-O-M linkage between the silicates and the metals are strong, polar-covalent bonds. Silicate anions ([SiO 2+n] 2n−) are invariably colorless, or when crushed to a fine powder, white. The colors of silicate minerals arise from the metal component, commonly iron. In most silicate minerals, silicon is tetrahedral, being surrounded by four ...
Phyllosilicates are sheet silicate minerals, formed by parallel sheets of silicate tetrahedra with Si 2 O 5 in a 2:5 ratio. Subcategories. This category has the ...
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al 2 Si 2 O 5 4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay minerals form in the presence of water [1] and have been important to life, and many theories of abiogenesis ...
Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm ; magnification of about 25,000 times, using an electron microscope, is required ...
Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. [ 5 ]
When treated with calcium oxides and water, silicate minerals form Portland cement. Equilibria involving hydrolysis of silicate minerals are difficult to study. The chief challenge is the very low solubility of SiO 4 4-and its various protonated forms. Such equilibria are relevant to the processes occurring on geological time scales.
Apophyllite has an unusual structure for a phyllosilicate. Whereas most phyllosilicates have a T layer (silica backbone) consisting of interlocked 6-fold rings of silica tetrahedra, with pseudohexagonal symmetry, the T layer in apophyllite consists of interlocked 4-fold and 8-fold rings of silica tetrahedra with true tetragonal symmetry.
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