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The copper–copper(II) sulfate electrode is a reference electrode of the first kind, [1] based on the redox reaction with participation of the metal and its salt, copper(II) sulfate. It is used for measuring electrode potential and is the most commonly used reference electrode for testing cathodic protection corrosion control systems. [2]
Cathodic protection (CP; / k æ ˈ θ ɒ d ɪ k / ⓘ) is a technique used to control the corrosion of a metal surface by making it the cathode of an electrochemical cell. [1] A simple method of protection connects the metal to be protected to a more easily corroded "sacrificial metal" to act as the anode. The sacrificial metal then corrodes ...
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]
Cathodic protection uses one or more sacrificial anodes made of a metal which is more active than the protected metal. Alloys of metals commonly used for sacrificial anodes include zinc, magnesium, and aluminium. This approach is commonplace in water heaters and many buried or immersed metallic structures.
Variations from these ideal conditions affect measured voltage via the Nernst equation. Electrode potentials of successive elementary half-reactions cannot be directly added. However, the corresponding Gibbs free energy changes (∆G°) must satisfy ∆G° = – z FE°,
The unshaded bars indicate the location on the chart of those steels when in acidic/stagnant water ( like in the bilge ), where crevice-corrosion happens. Notice how the *same* steel has much different galvanic-series location, depending on the electrolyte it's in, making prevention of corrosion .. more difficult.
Cathodic Protection: Cathodic protection is a technique used to protect metals from corrosion by applying a small electrical current to the metal surface. This technique can also help prevent SCC by reducing the corrosion potential of the metal. [7] Environmental Controls: Controlling the environment around the metal can help prevent SCC.
The process of pit nucleation is initiated by the depassivation of the protective oxide layer isolating the metal substrate from the aggressive solution. The depassivation of the protective oxide layer is the less properly understood step in pitting corrosion and its very local and random appearance probably its most enigmatic characteristic.