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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
Its standard deviation is 32.9 and its average is 27.9, giving a coefficient of variation of 32.9 / 27.9 = 1.18; In these examples, we will take the values given as the entire population of values. The data set [100, 100, 100] has a population standard deviation of 0 and a coefficient of variation of 0 / 100 = 0
The mean and the standard deviation of a set of data are descriptive statistics usually reported together. In a certain sense, the standard deviation is a "natural" measure of statistical dispersion if the center of the data is measured about the mean. This is because the standard deviation from the mean is smaller than from any other point.
The instrument detection limit (IDL) is the analyte concentration that is required to produce a signal greater than three times the standard deviation of the noise level. This may be practically measured by analyzing 8 or more standards at the estimated IDL then calculating the standard deviation from the measured concentrations of those standards.
The second standard deviation from the mean in a normal distribution encompasses a larger portion of the data, covering approximately 95% of the observations. Standard deviation is a widely used measure of the spread or dispersion of a dataset. It quantifies the average amount of variation or deviation of individual data points from the mean of ...
2 consecutive measurements exceed 2 standard deviations of the reference range, and on the same side of the mean. Inaccuracy and/or imprecision R 4s: Two measurements in the same run have a 4 standard deviation difference (such as one exceeding 2 standard deviations above the mean, and another exceeding 2 standard deviations below the mean).
σ g: Geometric standard deviation. This value is determined mathematically by the equation: σ g = D 84.13 /D 50 = D 50 /D 15.87. The value of σ g determines the slope of the least-squares regression curve. α: Relative standard deviation or degree of polydispersity. This value is also determined mathematically.
In statistics and in particular statistical theory, unbiased estimation of a standard deviation is the calculation from a statistical sample of an estimated value of the standard deviation (a measure of statistical dispersion) of a population of values, in such a way that the expected value of the calculation equals the true value.