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Malachite is a copper carbonate hydroxide mineral, with the formula Cu 2 CO 3 (OH) 2.This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation.
Both malachite and azurite, as well as synthetic basic copper carbonate have been used as pigments. [10] One example of the use of both azurite and its artificial form blue verditer [ 11 ] is the portrait of the family of Balthasar Gerbier by Peter Paul Rubens . [ 12 ]
Malachite green is an organic compound that is used as a dyestuff and controversially as an antimicrobial in aquaculture. Malachite green is traditionally used as a dye for materials such as silk, leather, and paper. Despite its name the dye is not prepared from the mineral malachite; the name just comes from the similarity of color.
The optical properties (color, intensity) of minerals such as azurite and malachite are characteristic of copper(II). Many coordination complexes of copper(II) exhibit similar colors. According to crystal field theory, the color results from low energy d-d transitions associated with the d 9 metal center. [12] [13]
Chrysocolla has a cyan (blue-green) color and is a minor ore of copper, having a hardness of 2.5 to 7.0. It is of secondary origin and forms in the oxidation zones of copper ore bodies. Associated minerals are quartz, limonite, azurite, malachite, cuprite, and other secondary copper minerals.
Chalcopyrite is a member of the tetragonal crystal system. Crystallographically the structure of chalcopyrite is closely related to that of zinc blende ZnS ( sphalerite ). [ 18 ] The unit cell is twice as large, reflecting an alternation of Cu + and Fe 3+ ions replacing Zn 2+ ions in adjacent cells.
Shattuckite crystals form concentric circular clusters of spraying, elongated, acicular crystals. Associated with them are small bits of contrasting primary malachite crystals in a deep green color Botryoidal balls of shattuckite, from the Kaokoveld Mine, Kaokoveld Plateau, Kunene Region , Namibia
Pseudomalachite is a phosphate of copper with hydroxyl, named from the Greek for "false" and "malachite", because of its similarity in appearance to the carbonate mineral malachite, Cu 2 (CO 3)(OH) 2. Both are green coloured secondary minerals found in oxidised zones of copper deposits, often associated with each other.
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