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The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation ...
The measurement of pH can become difficult at extremely acidic or alkaline conditions, such as below pH 2.5 (ca. 0.003 mol/dm 3 acid) or above pH 10.5 (above ca. 0.0003 mol/dm 3 alkaline). This is due to the breakdown of the Nernst equation in such conditions when using a glass electrode. Several factors contribute to this problem.
For example, two numbers can be multiplied just by using a logarithm table and adding. These are often known as logarithmic properties, which are documented in the table below. [2] The first three operations below assume that x = b c and/or y = b d, so that log b (x) = c and log b (y) = d. Derivations also use the log definitions x = b log b (x ...
For example, π(10) = 4 because there are four prime numbers (2, 3, 5 and 7) less than or equal to 10. The prime number theorem then states that x / log x is a good approximation to π(x) (where log here means the natural logarithm), in the sense that the limit of the quotient of the two functions π(x) and x / log x as x increases without ...
Because log(x) is the sum of the terms of the form log(1 + 2 −k) corresponding to those k for which the factor 1 + 2 −k was included in the product P, log(x) may be computed by simple addition, using a table of log(1 + 2 −k) for all k. Any base may be used for the logarithm table.
The Henderson–Hasselbalch equation can be used to model these equilibria. It is important to maintain this pH of 7.4 to ensure enzymes are able to work optimally. [10] Life threatening Acidosis (a low blood pH resulting in nausea, headaches, and even coma, and convulsions) is due to a lack of functioning of enzymes at a low pH. [10]
[c] [2] For example, a hypothetical weak acid having K a = 10 −5, the value of log K a is the exponent (−5), giving pK a = 5. For acetic acid, K a = 1.8 x 10 −5, so pK a is 4.7. A higher K a corresponds to a stronger acid (an acid that is more dissociated at equilibrium).
In mathematics, the common logarithm (aka "standard logarithm") is the logarithm with base 10. [1] It is also known as the decadic logarithm , the decimal logarithm and the Briggsian logarithm . The name "Briggsian logarithm" is in honor of the British mathematician Henry Briggs who conceived of and developed the values for the "common logarithm".