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In organic chemistry, a carbonyl group is a functional group with the formula C=O, composed of a carbon atom double-bonded to an oxygen atom, and it is divalent at the C atom. It is common to several classes of organic compounds (such as aldehydes, ketones and carboxylic acid), as part of many larger functional groups. A compound containing a ...
Triruthenium dodecacarbonyl is the chemical compound with the formula Ru 3 (CO) 12. Classified as metal carbonyl cluster, it is a dark orange-colored solid that is soluble in nonpolar organic solvents. The compound serves as a precursor to other organoruthenium compounds.
General structure of 1,2-, 1,3-, and 1,4-dicarbonyls. In organic chemistry, a dicarbonyl is a molecule containing two carbonyl (C=O) groups.Although this term could refer to any organic compound containing two carbonyl groups, it is used more specifically to describe molecules in which both carbonyls are in close enough proximity that their reactivity is changed, such as 1,2-, 1,3-, and 1,4 ...
Most metal carbonyl complexes contain a mixture of ligands. Examples include the historically important IrCl(CO)(P(C 6 H 5) 3) 2 and the antiknock agent (CH 3 C 5 H 4)Mn(CO) 3. The parent compounds for many of these mixed ligand complexes are the binary carbonyls, those species of the formula [M x (CO) n] z, many of which are
Acyl compounds react with nucleophiles via an addition mechanism: the nucleophile attacks the carbonyl carbon, forming a tetrahedral intermediate. This reaction can be accelerated by acidic conditions, which make the carbonyl more electrophilic , or basic conditions, which provide a more anionic and therefore more reactive nucleophile.
Dicobalt octacarbonyl is an organocobalt compound with composition Co 2 (CO) 8. This metal carbonyl is used as a reagent and catalyst in organometallic chemistry and organic synthesis, and is central to much known organocobalt chemistry. [2] [3] It is the parent member of a family of hydroformylation catalysts. [4]
Tungsten hexacarbonyl (also called tungsten carbonyl) is an organometallic compound with the formula W(CO) 6. This complex gave rise to the first example of a dihydrogen complex. [2] Like its chromium and molybdenum analogs, this colorless compound is noteworthy as a volatile, air-stable derivative of tungsten in its zero oxidation state.
Molybdenum hexacarbonyl (also called molybdenum carbonyl) is the chemical compound with the formula Mo(CO) 6. This colorless solid, like its chromium , tungsten , and seaborgium analogues, is noteworthy as a volatile, air-stable derivative of a metal in its zero oxidation state.
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