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Solid HP(O)(OH) 2 has tetrahedral geometry about the central phosphorus atom, with a P−H bond of 132 pm, one P=O double bond of 148 pm and two longer P−OH single bonds of 154 pm. In common with other phosphorus oxides with P−H bonds (e.g. hypophosphorous acid and dialkyl phosphites ), [ 2 ] it exists in equilibrium with an extremely minor ...
The last one is pyrophosphate [P 2 O 7] 4−. The pyrophosphates are mostly water-soluble. Likewise, tripolyphosphoric acid H 5 P 3 O 10 yields at least five anions [H 5−k P 3 O 10] k−, where k ranges from 1 to 5, including tripolyphosphate [P 3 O 10] 5−. Tetrapolyphosphoric acid H 6 P 4 O 13 yields at least six anions, including ...
In both cases the phosphoric acid solution usually contains 23–33% P 2 O 5 (32–46% H 3 PO 4). It may be concentrated to produce commercial-or merchant-grade phosphoric acid, which contains about 54–62% P 2 O 5 (75–85% H 3 PO 4). Further removal of water yields superphosphoric acid with a P 2 O 5 concentration above 70% (corresponding to ...
HPA is usually supplied as a 50% aqueous solution and heating at low temperatures (up to about 90 °C) prompts it to react with water to form phosphorous acid and hydrogen gas. H 3 PO 2 + H 2 O → H 3 PO 3 + H 2. Heating above 110 °C causes hypophosphorous acid to undergo disproportionation to give phosphorous acid and phosphine. [7] 3 H 3 PO ...
Hypophosphoric acid is a mineral acid with the formula H 4 P 2 O 6, with phosphorus in a formal oxidation state of +4. In the solid state it is present as the dihydrate, H 4 P 2 O 6 ·2H 2 O. In hypophosphoric acid the phosphorus atoms are identical and joined directly with a P−P bond.
Some phosphorus oxoacids have two or more P atoms in different oxidation states. One example is Isohypophosphoric acid, H 4 P 2 O 6 (or H(OH)(O)P−O−P(O)(OH) 2), a tetraprotic acid and isomer of hypophosphoric acid, containing P in oxidation state +3 and +5; Phosphoric anhydride P 4 O 10 Some phosphoric acids
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Vanadyl phosphate (VOPO 4 (H 2 O)) is a commercial catalyst for oxidation reactions. Many metal phosphates occur as minerals. ... Structure of [(C 6 H 6)Ru(P 3 O 9)] ...