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Iron is a chemical element; it has the symbol Fe ... Ruthenium exhibits an aqueous cationic chemistry in its low oxidation states similar to that of iron, ...
Prussian blue or "ferric ferrocyanide", Fe 4 [Fe(CN) 6] 3, is an old and well-known iron-cyanide complex, extensively used as pigment and in several other applications. Its formation can be used as a simple wet chemistry test to distinguish between aqueous solutions of Fe 2+ and Fe 3+ as they react (respectively) with potassium ferricyanide and ...
Thus ferrocyanide ([Fe(CN) 6] 4− has no unpaired electrons, meaning it is a low-spin complex. With so-called "weak field ligands" such as water, four of the six electrons are unpaired, meaning it is a high-spin complex. Thus aquo complex [Fe(H 2 O) 6] 2+ is paramagnetic. With chloride, iron(II) forms tetrahedral complexes, e.g. [FeCl 4] 2− ...
A molecular ferric complex is the anion ferrioxalate, [Fe(C 2 O 4) 3] 3−, with three bidentate oxalate ions surrounding the Fe core. Relative to lower oxidation states, ferric is less common in organoiron chemistry , but the ferrocenium cation [Fe(C 2 H 5 ) 2 ] + is well known.
There are 28 known radioactive isotopes and 8 nuclear isomers, the most stable of which are 60 Fe (half-life 2.6 million years) and 55 Fe (half-life 2.7 years). Much of the past work on measuring the isotopic composition of iron has centered on determining 60 Fe variations due to processes accompanying nucleosynthesis (i.e., meteorite studies ...
Iron allotropes, showing the differences in structure. The alpha iron (α-Fe) is a body-centered cubic (BCC) and the gamma iron (γ-Fe) is a face-centered cubic (FCC). At atmospheric pressure, three allotropic forms of iron exist, depending on temperature: alpha iron (α-Fe, ferrite), gamma iron (γ-Fe, austenite), and delta iron (δ-Fe).
The number of atoms of an element in a molecule or chemical compound is shown in the right subscript position (e.g., N 2 or Fe 2 O 3). If this number is one, it is normally omitted - the number one is implicitly understood if unspecified. A radical is indicated by a dot on the right side (e.g., Cl • for a neutral chlorine atom).
The red lepidocrocite (γ-Fe(O)OH) occurs on the outside of rusticles, and the orange goethite (α-Fe(O)OH) occurs internally in rusticles. When Fe 2 O 3 ·H 2 O is heated, it loses its water of hydration. Further heating at 1670 K converts Fe 2 O 3 to black Fe 3 O 4 (Fe II Fe III 2 O 4), which is known as the mineral magnetite.
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