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  2. Joule–Thomson effect - Wikipedia

    en.wikipedia.org/wiki/Joule–Thomson_effect

    The rate of change of temperature with respect to pressure in a Joule–Thomson process (that is, at constant enthalpy ) is the Joule–Thomson (Kelvin) coefficient. This coefficient can be expressed in terms of the gas's specific volume V {\displaystyle V} , its heat capacity at constant pressure C p {\displaystyle C_{\mathrm {p} }} , and its ...

  3. Table of thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Table_of_thermodynamic...

    Defining equation SI unit Dimension ... J ML 2 T −2: Enthalpy: H = + J ML 2 T −2: Partition Function: Z: 1 1 Gibbs free energy: G = J ML 2 T ...

  4. Inversion temperature - Wikipedia

    en.wikipedia.org/wiki/Inversion_temperature

    This temperature change is known as the Joule–Thomson effect, and is exploited in the liquefaction of gases. Inversion temperature depends on the nature of the gas. For a van der Waals gas we can calculate the enthalpy using statistical mechanics as

  5. Enthalpy - Wikipedia

    en.wikipedia.org/wiki/Enthalpy

    Enthalpy (/ ˈ ɛ n θ əl p i / ⓘ) is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. [1] It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant external pressure, which is conveniently provided by the large ambient atmosphere.

  6. Thermodynamic equations - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_equations

    Only one equation of state will not be sufficient to reconstitute the fundamental equation. All equations of state will be needed to fully characterize the thermodynamic system. Note that what is commonly called "the equation of state" is just the "mechanical" equation of state involving the Helmholtz potential and the volume:

  7. Thermodynamic databases for pure substances - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_databases...

    Thermodynamic databases contain information about thermodynamic properties for substances, the most important being enthalpy, entropy, and Gibbs free energy.Numerical values of these thermodynamic properties are collected as tables or are calculated from thermodynamic datafiles.

  8. Thermochemical equation - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_equation

    In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings. One such equation involves the enthalpy change, which is denoted with Δ H {\displaystyle \Delta H} In variable form, a thermochemical equation would appear similar to the following:

  9. Fundamental thermodynamic relation - Wikipedia

    en.wikipedia.org/wiki/Fundamental_thermodynamic...

    This equation has been derived in the case of reversible changes. However, since U , S , and V are thermodynamic state functions that depend on only the initial and final states of a thermodynamic process, the above relation holds also for non-reversible changes.