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These occur due to chance when electrons happen to be more concentrated in one place than another in a molecule, creating a temporary dipole. These dipoles are smaller in magnitude than permanent dipoles, but still play a large role in chemistry and biochemistry due to their prevalence. See instantaneous dipole. Induced dipoles
The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. ...
In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized . [ 1 ]
The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.
The electric potential and the magnetic vector potential together form a four-vector, so that the two kinds of potential are mixed under Lorentz transformations. Practically, the electric potential is a continuous function in all space, because a spatial derivative of a discontinuous electric potential yields an electric field of impossibly ...
In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
Due to polarization the positive bound charge + will be displaced a distance relative to the negative bound charge , giving rise to a dipole moment =. Substitution of this expression in (1) yields P = d q b d V d {\displaystyle \mathbf {P} ={\mathrm {d} q_{b} \over \mathrm {d} V}\mathbf {d} }
The transition dipole moment is useful for determining if transitions are allowed under the electric dipole interaction. For example, the transition from a bonding π {\displaystyle \pi } orbital to an antibonding π ∗ {\displaystyle \pi ^{*}} orbital is allowed because the integral defining the transition dipole moment is nonzero.