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Several vanadium(IV) phosphates are known. These materials are typically blue. In these species, the phosphate anion is singly or doubly protonated. Examples include the hydrogenphosphates, VOHPO 4. 4H 2 O and VO(HPO 4). 0.5H 2 O, as well as the dihydrogen phosphate VO(H 2 PO 4) 2. Portion of the crystal structure of VO(HPO 4). 0.5H 2 O. The ...
Metal aqua ions are always accompanied in solution by solvated anions, but much less is known about anion solvation than about cation solvation. [ 6 ] Understanding of the nature of aqua ions is helped by having information on the nature of solvated cations in mixed solvents [ 7 ] and non-aqueous solvents , such as liquid ammonia , methanol ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
According to their properties, cations are usually classified into six groups. [1] Each group has a common reagent which can be used to separate them from the solution.To obtain meaningful results, the separation must be done in the sequence specified below, as some ions of an earlier group may also react with the reagent of a later group, causing ambiguity as to which ions are present.
The incidence of positively charged ions (cations, oxycations and hydroxycations) and negatively charged ions (anions, oyxanions and hydroxyanions) in each block of the periodic table shows a left to right decline of positively charged ions and increase in negatively charged species, This pattern is consistent with a left to right progression ...
The target analytes (anions or cations) are retained on the stationary phase but can be eluted by increasing the concentration of a similarly charged species that displaces the analyte ions from the stationary phase. For example, in cation exchange chromatography, the positively charged analyte can be displaced by adding positively charged ...
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For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.