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Covalent radius: the nominal radius of the atoms of an element when covalently bound to other atoms, as deduced from the separation between the atomic nuclei in molecules. In principle, the distance between two atoms that are bound to each other in a molecule (the length of that covalent bond) should equal the sum of their covalent radii. [13]
The calculation is exemplified for silicon, whose relative atomic mass is especially important in metrology. Silicon exists in nature as a mixture of three isotopes: 28 Si, 29 Si and 30 Si. The atomic masses of these nuclides are known to a precision of one part in 14 billion for 28 Si and about one part in one billion for the others.
The gram-atom is a former term for a mole of atoms, and gram-molecule for a mole of molecules. [ 7 ] Molecular weight (M.W.) (for molecular compounds) and formula weight (F.W.) (for non-molecular compounds), are older terms for what is now more correctly called the relative molar mass ( M r ). [ 8 ]
The molar mass is defined as the mass of a given substance divided by the amount of the substance, and is expressed in grams per mol (g/mol). That makes the molar mass an average of many particles or molecules (potentially containing different isotopes ), and the molecular mass the mass of one specific particle or molecule.
Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
When compared to the average mass per nucleon in carbon-12, which is moderately strongly-bound compared with other atoms, the mass defect of binding for most atoms is an even smaller fraction of a dalton (unified atomic mass unit, based on carbon-12).
Wigner–Seitz radius is related to the electronic density by the formula r s = 0.62035 ρ 1 / 3 {\displaystyle r_{s}=0.62035\rho ^{1/3}} where, ρ can be regarded as the average electronic density in the outer portion of the Wigner-Seitz cell.
The value was chosen on the basis of the historical definition of the mole as the amount of substance that corresponds to the number of atoms in 12 grams of 12 C, [1] which made the mass of a mole of a compound expressed in grams, numerically equal to the average molecular mass or formula mass of the compound expressed in daltons.