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The chelate effect is the greater affinity of chelating ligands for a metal ion than that of similar nonchelating (monodentate) ligands for the same metal. The thermodynamic principles underpinning the chelate effect are illustrated by the contrasting affinities of copper (II) for ethylenediamine (en) vs. methylamine .
The macrocyclic effect is the high affinity of metal cations for macrocyclic ligands, compared to their acyclic analogues. [7] [8] The high affinity of macrocyclic ligands is thought to be a combination of the entropic effect seen in the chelate effect, together with an additional energetic contribution that comes from the preorganized nature of the ligating groups (that is, no additional ...
The science fiction studies is the critical assessment interpretation, and discussion of science fiction literature, film, TV shows, new media, fandom, and fan fiction. [215] Science fiction scholars study science fiction to better understand it and its relationship to science, technology, politics, other genres, and culture-at-large. [216]
Defining “science fiction” (so that one can say, definitively, this book is a sci-fi book) is a little like defining “spiritual” or some other vague belief category that includes so many ...
Science in science fiction is the study or of how science is portrayed in works of science fiction, including novels, stories, and films. It covers a large range of topics. Hard science fiction is based on engineering or the "hard" sciences (for example, physics, astronomy, or chemistry).
Science Fiction Literature through History: An Encyclopedia is a 2021 reference work written by science fiction scholar Gary Westfahl and published by ABC-Clio/Greenwood.The book contains eight essays on the history of science fiction, eleven thematic essays on how different topics relate to science fiction, and 250 entries on various science fiction subgenres, authors, works, and motifs.
Science fiction genre – while science fiction is a genre of fiction, a science fiction genre is a subgenre within science fiction. Science fiction may be divided along any number of overlapping axes. Gary K. Wolfe's Critical Terms for Science Fiction and Fantasy identifies over 30 subdivisions of science fiction, not including science fantasy ...
"A science fiction story is a story built around human beings, with a human problem, and a human solution, which would not have happened at all without its scientific content." [13] Basil Davenport. 1955. "Science fiction is fiction based upon some imagined development of science, or upon the extrapolation of a tendency in society." [14] Edmund ...