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When determining the stability constants of metal-ligand complexes, it is common practice to fix ligand protonation constants at values that have been determined using data obtained from metal-free solutions. Hydrolysis constants of metal ions are usually fixed at values which were obtained using ligand-free solutions.
The whirling frequency of a symmetric cross section of a given length between two points is given by: = where: E = Young's modulus, I = second moment of area, m = mass of the shaft, L = length of the shaft between points.
Specific impulse and effective exhaust velocity are dependent on the nozzle design unlike the characteristic velocity, explaining why C-star is an important value when comparing different propulsion system efficiencies. c* can be useful when comparing actual combustion performance to theoretical performance in order to determine how completely ...
The protonation of isobutene in the formation of a carbocation: (CH 3) 2 C=CH 2 + HBF 4 ⇌ (CH 3) 3 C + + BF − 4; The protonation of ammonia in the formation of ammonium chloride from ammonia and hydrogen chloride: NH 3 + HCl → NH 4 Cl; Protonation is a fundamental chemical reaction and is a step in many stoichiometric and catalytic processes.
The profile of the curve is determined by the c-value, which is calculated using the equation: c = n K a M {\displaystyle c=nK_{a}M} where n {\displaystyle n} is the stoichiometry of the binding, K a {\displaystyle K_{a}} is the association constant and M {\displaystyle M} is the concentration of the molecule in the cell.
The Gurney equations relate the following quantities: C - The mass of the explosive charge M - The mass of the accelerated shell or sheet of material (usually metal). The shell or sheet is often referred to as the flyer, or flyer plate. V or V m - Velocity of accelerated flyer after explosive detonation
The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
In other words, the electrical mobility of the particle is defined as the ratio of the drift velocity to the magnitude of the electric field: =. For example, the mobility of the sodium ion (Na + ) in water at 25 °C is 5.19 × 10 −8 m 2 /(V·s) . [ 1 ]