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Hydrogen sulfide is a chemical compound with the formula H 2 S. It is a colorless chalcogen-hydride gas , and is toxic, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs . [ 11 ]
Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: S 2− + H + → SH − SH − + H + → H 2 S. Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and ...
The structure of hydrogen disulfide is similar to that of hydrogen peroxide, with C 2 point group symmetry. Both molecules are distinctly nonplanar. The dihedral angle between the H a −S−S and S−S−H b planes is 90.6°, compared with 111.5° in H 2 O 2. The H−S−S bond angle is 92°, close to 90° for unhybridized divalent sulfur. [1]
At temperatures above 360 K, NaSH adopts the NaCl structure, which implies that the HS − behaves as a spherical anion owing to its rapid rotation, leading to equal occupancy of eight equivalent positions. Below 360 K, a rhombohedral structure forms, and the HS − sweeps out a discoidal shape. Below 114 K, the structure becomes monoclinic.
Such reactions are conducted in the presence of acidic catalysts. The other principal route to thiols involves the addition of hydrogen sulfide to alkenes. Such reactions are usually conducted in the presence of an acid catalyst or UV light. Halide displacement, using the suitable organic halide and sodium hydrogen sulfide has also been used. [23]
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
Potassium hydrosulfide is an inorganic compound with the formula KSH. This colourless salt consists of the cation K + and the bisulfide anion [SH] −.It is the product of the half-neutralization of hydrogen sulfide with potassium hydroxide.
At physiological pH, hydrogen sulfide is usually fully ionized to bisulfide (HS −). Therefore, in biochemical settings, "hydrogen sulfide" is often used to mean, bisulfide. Hydrosulfide has been identified as the third gasotransmitter along with nitric oxide and carbon monoxide. [5]