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A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
To attempt to simplify and to stylize a very complex set of various reactions, the whole ASR reaction, after its complete evolution (ageing process) in the presence of sufficient Ca 2+ cations available in solution, could be compared to the pozzolanic reaction which would be catalysed by the undesirable presence of excessive concentrations of alkali hydroxides (NaOH and KOH) in the concrete.
Structure of an octahedral metal aquo complex. Chromium(II) ion in aqueous solution. Most aquo complexes are mono-nuclear, with the general formula [M(H 2 O) 6] n+, with n = 2 or 3; they have an octahedral structure. The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond ...
This table lists the ionic species that are most likely to be present, depending on pH, in aqueous solutions of binary salts of metal ions. The existence must be inferred on the basis of indirect evidence provided by modelling with experimental data or by analogy with structures obtained by X-ray crystallography.
The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol ( vitriol is an archaic name for hydrated sulfate minerals ), the blue-green heptahydrate ( hydrate with 7 molecules of water) is the most common form of this material.
In aqueous solution, all forms of zinc sulfate behave identically. These aqueous solutions consist of the metal aquo complex [Zn(H 2 O) 6] 2+ and SO 2− 4 ions. Barium sulfate forms when these solutions are treated with solutions of barium ions: ZnSO 4 + BaCl 2 → BaSO 4 + ZnCl 2. With a reduction potential of −0.76 V, zinc(II) reduces only ...
Aqueous solutions of iron(III) chloride are also produced industrially from a number of iron precursors, including iron oxides: Fe 2 O 3 + 6 HCl + 9 H 2 O → 2 FeCl 3 (H 2 O) 6. In complementary route, iron metal can be oxidized by hydrochloric acid followed by chlorination: [10] Fe + 2 HCl → FeCl 2 + H 2 FeCl 2 + 0.5 Cl 2 + 6 H 2 O → FeCl ...
It can also be prepared from an aqueous solution of ammonium nitrate, and calcium hydroxide: 2 NH 4 NO 3 + Ca(OH) 2 → Ca(NO 3) 2 + 2 NH 4 OH. Like related alkaline earth metal nitrates, calcium nitrate decomposes upon heating (starting at 500 °C) to release nitrogen dioxide: [3] 2 Ca(NO 3) 2 → 2 CaO + 4 NO 2 + O 2 ΔH = 369 kJ/mol