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Potassium iodide is highly soluble in water thus SSKI is a concentrated source of KI. At 20 degrees Celsius the solubility of KI is 140-148 grams per 100 grams of water. [ 56 ] Because the volumes of KI and water are approximately additive, the resulting SSKI solution will contain about 1.00 gram (1000 mg) KI per milliliter (mL) of solution.
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Its formation explains why the solubility of iodine in water may be increased by the addition of potassium iodide solution: [11] I 2 + I − ⇌ I − 3 (K eq = ~700 at 20 °C) Many other polyiodides may be found when solutions containing iodine and iodide crystallise, such as I − 5, I − 9, I 2− 4, and I 2−
Elemental iodine is slightly soluble in water, with one gram dissolving in 3450 mL at 20 °C and 1280 mL at 50 °C; potassium iodide may be added to increase solubility via formation of triiodide ions, among other polyiodides. [25] Nonpolar solvents such as hexane and carbon tetrachloride provide a higher solubility. [26]
The solubility of a specific solute in a specific solvent is generally expressed as the concentration of a saturated solution of the two. [1] Any of the several ways of expressing concentration of solutions can be used, such as the mass, volume, or amount in moles of the solute for a specific mass, volume, or mole amount of the solvent or of the solution.
Potassium iodide renders the elementary iodine soluble in water through the formation of the triiodide (I − 3) ion. It is not to be confused with tincture of iodine solutions, which consist of elemental iodine, and iodide salts dissolved in water and alcohol. Lugol's solution contains no alcohol.
In solid phases, precipitation occurs if the concentration of one solid is above the solubility limit in the host solid, due to e.g. rapid quenching or ion implantation, and the temperature is high enough that diffusion can lead to segregation into precipitates. Precipitation in solids is routinely used to synthesize nanoclusters.