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Bioorganic chemistry is a scientific discipline that combines organic chemistry and biochemistry. It is that branch of life science that deals with the study of biological processes using chemical methods. [1] Protein and enzyme function are examples of these processes. [2]
In biochemistry and in biological fluids, at pH = 7, it is thus important to note that the reduction potential of the protons ( H +) into hydrogen gas H 2 is no longer zero as with the standard hydrogen electrode (SHE) at 1 M H + (pH = 0) in classical electrochemistry, but that E red = − 0.414 V {\displaystyle E_{\text{red}}=-0.414\mathrm {V ...
The Suzuki reaction or Suzuki coupling is an organic reaction that uses a palladium complex catalyst to cross-couple a boronic acid to an organohalide. [1] [2] [3] It was first published in 1979 by Akira Suzuki, and he shared the 2010 Nobel Prize in Chemistry with Richard F. Heck and Ei-ichi Negishi for their contribution to the discovery and development of noble metal catalysis in organic ...
In organic chemistry, a rearrangement reaction is a broad class of organic reactions where the carbon skeleton of a molecule is rearranged to give a structural isomer of the original molecule. [1] Often a substituent moves from one atom to another atom in the same molecule, hence these reactions are usually intramolecular. In the example below ...
Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms. [1]
Decarboxylation. Decarboxylation is a chemical reaction that removes a carboxyl group and releases carbon dioxide (CO 2).Usually, decarboxylation refers to a reaction of carboxylic acids, removing a carbon atom from a carbon chain.
In organic chemistry, a sigmatropic reaction (from Greek τρόπος (trópos) 'turn') is a pericyclic reaction wherein the net result is one sigma bond (σ-bond) is changed to another σ-bond in an intramolecular reaction. [1]
In the original paper describing this reaction, methylmagnesium bromide is reacted with isophorone with and without 1 mole percent of added copper(I) chloride (see figure). [ 10 ] Without added salt the main products are alcohol B (42%) from nucleophilic addition to the carbonyl group and diene C (48%) as its dehydration reaction product.