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Buffer capacity falls to 33% of the maximum value at pH = pK a ± 1, to 10% at pH = pK a ± 1.5 and to 1% at pH = pK a ± 2. For this reason the most useful range is approximately pK a ± 1. When choosing a buffer for use at a specific pH, it should have a pK a value as close as possible to that pH. [2]
The buffering capacity of a soil depends on the clay content of the soil, the type of clay, and the amount of organic matter present, and may be related to the soil cation exchange capacity. Soils with high clay content will have a higher buffering capacity than soils with little clay, and soils with high organic matter will have a higher ...
Acid-neutralizing capacity or ANC in short is a measure for the overall buffering capacity against acidification of a solution, e.g. surface water or soil water.. ANC is defined as the difference between cations of strong bases and anions of strong acids (see below), or dynamically as the amount of acid needed to change the pH value from the sample's value to a chosen different value. [1]
McIlvaine buffer is a buffer solution composed of citric acid and disodium hydrogen phosphate, also known as citrate-phosphate buffer. It was introduced in 1921 by the United States agronomist Theodore Clinton McIlvaine (1875–1959) from West Virginia University , and it can be prepared in pH 2.2 to 8 by mixing two stock solutions.
Structure liming can reduce losses of clay and nutrients from soil aggregates. [3] The degree to which a given amount of lime per unit of soil volume will increase soil pH depends on the buffer capacity of the soil (this is generally related to soil cation exchange capacity or CEC). Most acid soils are saturated with aluminum rather than ...
Soil texture affects soil behaviour, in particular, its retention capacity for nutrients (e.g., cation exchange capacity) [8] and water. Sand and silt are the products of physical and chemical weathering of the parent rock ; [ 9 ] clay, on the other hand, is most often the product of the precipitation of the dissolved parent rock as a secondary ...
Good's buffers (also Good buffers) are twenty buffering agents for biochemical and biological research selected and described by Norman Good and colleagues during 1966–1980. [ 1 ] [ 2 ] [ 3 ] Most of the buffers were new zwitterionic compounds prepared and tested by Good and coworkers for the first time, though some ( MES , ADA , BES , Bicine ...
Universal buffers consist of mixtures of acids of diminishing strength (increasing pK a), so that the change in pH is approximately proportional to the amount of alkali added. It consists of a mixture of 0.04 M boric acid, 0.04 M phosphoric acid and 0.04 M acetic acid that has been titrated to the desired pH with 0.2 M sodium hydroxide. Britton ...