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Polyethylene was first synthesized by the German chemist Hans von Pechmann, who prepared it by accident in 1898 while investigating diazomethane. [12] [a] [13] [b] When his colleagues Eugen Bamberger and Friedrich Tschirner characterized the white, waxy substance that he had created, they recognized that it contained long −CH 2 − chains and termed it polymethylene.
HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
Polyethylene terephthalate is produced largely from purified terephthalic acid (PTA), as well as to a lesser extent from (mono-)ethylene glycol (MEG) and dimethyl terephthalate (DMT). [ 41 ] [ 5 ] As of 2022, ethylene glycol is made from ethene found in natural gas , while terephthalic acid comes from p-xylene made from crude oil .
Engineering plastics [1] are a group of plastic materials that have better mechanical or thermal properties than the more widely used commodity plastics (such as polystyrene, polyvinyl chloride, polypropylene and polyethylene). Engineering plastics are more expensive than standard plastics, therefore they are produced in lower quantities and ...
Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene. It was the first grade of polyethylene , produced in 1933 by John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization . [ 1 ]
Polymer engineering is generally an engineering field that designs, analyses, and modifies polymer materials. Polymer engineering covers aspects of the petrochemical industry, polymerization, structure and characterization of polymers, properties of polymers, compounding and processing of polymers and description of major polymers, structure property relations and applications.
The Properties of Polyethylene Crystallized Under the Orientation and Pressure Effects of a Pressure Capillary Viscometer, Journal of Applied Polymer Science vol. 14, pp. 2305–2317 (1970). Kanamoto, On Ultra-High Tensile by Drawing Single Crystal Mats of High Molecular Weight Polyethylene, Polymer Journal vol. 15, No. 4, pp. 327–329 (1983).
The mechanical properties of a polymer are strongly dependent upon the Van der Waals interactions of the polymer chains, and the ability of the chains to elongate and align in the direction of the applied force. Other phenomena, such as the propensity of polymers to form crazes can impact the mechanical properties.