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Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
An aqueous solution containing 120 mg NaHCO 3 (baking soda) per litre of water will contain 1.4285 mmol/l of bicarbonate, since the molar mass of baking soda is 84.007 g/mol. This is equivalent in carbonate hardness to a solution containing 0.71423 mmol/L of (calcium) carbonate, or 71.485 mg/L of calcium carbonate (molar mass 100.09 g/mol).
Burning (calcination) of calcium carbonate in a lime kiln above 900 °C (1,650 °F) [4] converts it into the highly caustic material burnt lime, unslaked lime or quicklime (calcium oxide) and, through subsequent addition of water, into the less caustic (but still strongly alkaline) slaked lime or hydrated lime (calcium hydroxide, Ca(OH) 2), the ...
Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
where the solubility product for [Ca 2+][CO 2− 3] is given as anywhere from K sp = 3.7 × 10 −9 to K sp = 8.7 × 10 −9 at 25 °C, depending upon the data source. [ 80 ] [ 81 ] What the equation means is that the product of molar concentration of calcium ions ( moles of dissolved Ca 2+ per liter of solution) with the molar concentration of ...
CO 2 + Ca(OH) 2 → CaCO 3 + H 2 O + heat (in the presence of water) Each mole of CO 2 (44 g) reacts with one mole of calcium hydroxide (74 g) and produces one mole of water (18 g). The reaction can be considered as a strong-base-catalysed, water-facilitated reaction.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Magnesium gluconate – Mg(HOCH 2 (CHOH) 4 CO 2) 2; Magnesium hydride – MgH 2; Dimagnesium phosphate – MgHPO 4; Magnesium hydroxide – Mg(OH) 2; Magnesium hypochlorite – Mg(OCl) 2; Magnesium iodide – MgI 2; Magnesium molybdate – MgMoO 4; Magnesium nitrate – Mg(NO 3) 2; Magnesium oxalate – MgC 2 O 4; Magnesium peroxide – MgO 2 ...