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Each element has a characteristic set of spectral lines, so stellar spectroscopy can be used to infer the atmospheric composition of individual stars. Observations indicate a strong negative correlation between a star's initial heavy element content (known as the metallicity) and its age. More recently formed stars tend to have higher metallicity.
The word correlation energy has to be used with caution. First it is usually defined as the energy difference of a correlated method relative to the Hartree–Fock energy. But this is not the full correlation energy because some correlation is already included in HF. Secondly the correlation energy is highly dependent on the basis set used. The ...
Heavy metals is a controversial and ambiguous term [2] for metallic elements with relatively high densities, atomic weights, or atomic numbers.The criteria used, and whether metalloids are included, vary depending on the author and context and it has been argued that the term "heavy metal" should be avoided.
In astronomy, metallicity is the abundance of elements present in an object that are heavier than hydrogen and helium. Most of the normal currently detectable (i.e. non-dark) matter in the universe is either hydrogen or helium, and astronomers use the word "metals" as convenient shorthand for "all elements except hydrogen and helium".
The perovskite structure of BSCCO, a high-temperature superconductor and a strongly correlated material.. Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual (often technologically useful) electronic and magnetic properties, such as metal-insulator transitions, heavy fermion behavior, half-metallicity, and spin-charge ...
If heavy element chemistry were a sports franchise, they won the world championships with calcium 48, and then had to take time to rebuild after everyone retired. Now, a new generation of players ...
Relativistic quantum chemistry combines relativistic mechanics with quantum chemistry to calculate elemental properties and structure, especially for the heavier elements of the periodic table. A prominent example is an explanation for the color of gold: due to relativistic effects, it is not silvery like most other metals. [1]
The Mulliken electronegativity can only be calculated for an element whose electron affinity is known. Measured values are available for 72 elements, while approximate values have been estimated or calculated for the remaining elements. The Mulliken electronegativity of an atom is sometimes said to be the negative of the chemical potential. [14]