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Free electron model. In solid-state physics, the free electron model is a quantum mechanical model for the behaviour of charge carriers in a metallic solid. It was developed in 1927, [1] principally by Arnold Sommerfeld, who combined the classical Drude model with quantum mechanical Fermi–Dirac statistics and hence it is also known as the ...
In physics, the Wiedemann–Franz law states that the ratio of the electronic contribution of the thermal conductivity (κ) to the electrical conductivity (σ) of a metal is proportional to the temperature (T). [1] Theoretically, the proportionality constant L, known as the Lorenz number, is equal to. where kB is the Boltzmann constant and e is ...
Marcus theory is used to describe a number of important processes in chemistry and biology, including photosynthesis, corrosion, certain types of chemiluminescence, charge separation in some types of solar cells and more. Besides the inner and outer sphere applications, Marcus theory has been extended to address heterogeneous electron transfer.
Drude formula is derived in a limited way, namely by assuming that the charge carriers form a classical ideal gas. When quantum theory is considered, the Drude model can be extended to the free electron model, where the carriers follow Fermi–Dirac distribution. The conductivity predicted is the same as in the Drude model because it does not ...
The Bohr–Sommerfeld model (also known as the Sommerfeld model or Bohr–Sommerfeld theory) was an extension of the Bohr model to allow elliptical orbits of electrons around an atomic nucleus. Bohr–Sommerfeld theory is named after Danish physicist Niels Bohr and German physicist Arnold Sommerfeld. Sommerfeld argued that if electronic orbits ...
In condensed matter physics, Bloch's theorem states that solutions to the Schrödinger equation in a periodic potential can be expressed as plane waves modulated by periodic functions. The theorem is named after the Swiss physicist Felix Bloch, who discovered the theorem in 1929. [1] Mathematically, they are written [2] Bloch function.
The difficulty encountered by the Drude model, the electronic theory of metals at that time, was due to considering that electrons were (according to classical statistics theory) all equivalent. In other words, it was believed that each electron contributed to the specific heat an amount on the order of the Boltzmann constant k B. This problem ...
Thomson scattering is a model for the effect of electromagnetic fields on electrons when the field energy is much less than the rest mass of the electron .In the model the electric field of the incident wave accelerates the charged particle, causing it, in turn, to emit radiation at the same frequency as the incident wave, and thus the wave is scattered.