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The Seebeck coefficient (also known as thermopower, [1] thermoelectric power, and thermoelectric sensitivity) of a material is a measure of the magnitude of an induced thermoelectric voltage in response to a temperature difference across that material, as induced by the Seebeck effect. [2] The SI unit of the Seebeck coefficient is volts per ...
Thermoelectric materials [1][2] show the thermoelectric effect in a strong or convenient form. The thermoelectric effect refers to phenomena by which either a temperature difference creates an electric potential or an electric current creates a temperature difference. These phenomena are known more specifically as the Seebeck effect (creating a ...
The Peltier and Seebeck coefficients can only be easily determined for pairs of materials; hence, it is difficult to find values of absolute Seebeck or Peltier coefficients for an individual material. If the Thomson coefficient of a material is measured over a wide temperature range, it can be integrated using the Thomson relations to determine ...
A thermoelectric generator (TEG), also called a Seebeck generator, is a solid state device that converts heat (driven by temperature differences) directly into electrical energy through a phenomenon called the Seebeck effect [1] (a form of thermoelectric effect). Thermoelectric generators function like heat engines, but are less bulky and have ...
Impurities affect each batch of metal differently, producing variable Seebeck coefficients. To match the standard behaviour, thermocouple wire manufacturers will deliberately mix in additional impurities to "dope" the alloy, compensating for uncontrolled variations in source material. [5]
Due to this, bismuth-telluride-based materials used for power generation or cooling applications must be polycrystalline. Furthermore, the Seebeck coefficient of bulk Bi 2 Te 3 becomes compensated around room temperature, forcing the materials used in power-generation devices to be an alloy of bismuth, antimony, tellurium, and selenium. [5]
Thermoelectric cooling uses the Peltier effect to create a heat flux at the junction of two different types of materials. A Peltier cooler, heater, or thermoelectric heat pump is a solid-state active heat pump which transfers heat from one side of the device to the other, with consumption of electrical energy, depending on the direction of the current.
Onsager's reciprocity in the thermoelectric effect manifests itself in the equality of the Peltier (heat flow caused by a voltage difference) and Seebeck (electric current caused by a temperature difference) coefficients of a thermoelectric material.