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Atomic, molecular, and optical physics (AMO) is the study of matter–matter and light–matter interactions, at the scale of one or a few atoms [1] and energy scales around several electron volts. [ 2 ] : 1356 [ 3 ] The three areas are closely interrelated.
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
The incoming light excites a polarization that can be described with the semiconductor Bloch equations. [8] [9] Once the photons are absorbed, electrons and holes are formed with finite momenta in the conduction and valence bands, respectively. The excitations then undergo energy and momentum relaxation towards the band-gap minimum.
Modern physical chemistry originated in the 1860s to 1880s with work on chemical thermodynamics, electrolytes in solutions, chemical kinetics and other subjects. One milestone was the publication in 1876 by Josiah Willard Gibbs of his paper, On the Equilibrium of Heterogeneous Substances .
The absorption of light is due to the interaction of light with the electronic and vibrational modes of molecules. Each type of molecule has an individual set of energy levels associated with the makeup of its chemical bonds and nuclei and thus will absorb light of specific wavelengths, or energies, resulting in unique spectral properties. [ 5 ]
A photon (from Ancient Greek φῶς, φωτός (phôs, phōtós) 'light') is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force.
Light exerts physical pressure on objects in its path, a phenomenon which can be deduced by Maxwell's equations, but can be more easily explained by the particle nature of light: photons strike and transfer their momentum. Light pressure is equal to the power of the light beam divided by c, the speed of light.
In contrast, the term luminescence (from the Latin lumen for "light"), was coined by Eilhardt Wiedemann in 1888 as a term to refer to "light without heat", while "fluorescence" by Sir George Stokes in 1852, when he noticed that, when exposing a solution of quinine sulfate to light refracted through a prism, the solution glowed when exposed to ...