Search results
Results from the WOW.Com Content Network
The limiting reagent (or limiting reactant or limiting agent) in a chemical reaction is a reactant that is totally consumed when the chemical reaction is completed. [ 1 ] [ 2 ] The amount of product formed is limited by this reagent, since the reaction cannot continue without it.
Because a lesser amount of PbO is produced for the 200.0 g of PbS, it is clear that PbS is the limiting reagent. In reality, the actual yield is not the same as the stoichiometrically-calculated theoretical yield. Percent yield, then, is expressed in the following equation:
The limiting reagent determines the theoretical yield—the relative quantity of moles of reactants and the product formed in a chemical reaction. Other reactants are said to be present in excess. The actual yield—the quantity physically obtained from a chemical reaction conducted in a laboratory—is often less than the theoretical yield. [8]
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
[2] [8] [9] While reaction calorimetry is less frequently employed than a number of other techniques, it has found use as an effective tool for catalyst screening. [10] Reaction calorimetry has also been applied as an efficient method for mechanistic study of individual reactions including the prolinate - catalyzed α- amination of aldehydes ...
The amount produced by chemical synthesis is known as the reaction yield. Typically, yields are expressed as a mass in grams (in a laboratory setting) or as a percentage of the total theoretical quantity that could be produced based on the limiting reagent. [2] A side reaction is an
Figure 1: View of Drucker–Prager yield surface in 3D space of principal stresses for =, = The Drucker–Prager yield criterion [1] is a pressure-dependent model for determining whether a material has failed or undergone plastic yielding. The criterion was introduced to deal with the plastic deformation of soils.
The selectivity of this reagent is illustrated by its reduction of all three methylcyclohexanones to the less stable methylcyclohexanols in >98% yield. Under certain conditions, L-selectride can selectively reduce enones by conjugate addition of hydride, owing to the greater steric hindrance the bulky hydride reagent experiences at the carbonyl ...