Search results
Results from the WOW.Com Content Network
The negatively charged halide ion shields the carbocation from being attacked on the front side, and backside attack, which leads to inversion of configuration, is preferred. Thus the actual product no doubt consists of a mixture of enantiomers but the enantiomers with inverted configuration would predominate and complete racemization does not ...
With standard S N 1 reaction conditions the reaction outcome is retention via a competing S N i mechanism and not racemization and with pyridine added the result is again inversion. [5] [3] S N i reaction mechanism Sn1 occurs in tertiary carbon while Sn2 occurs in primary carbon
Sigmatropic rearrangements are concisely described by an order term [i,j], which is defined as the migration of a σ-bond adjacent to one or more π systems to a new position (i−1) and (j−1) atoms removed from the original location of the σ-bond. [3]
In the Walden inversion, the backside attack by the nucleophile in an S N 2 reaction gives rise to a product whose configuration is opposite to the reactant. Therefore, during S N 2 reaction, 100% inversion of product takes place. This is known as Walden inversion. It was first observed by chemist Paul Walden in 1896.
Evolutionary epistemology of theories assumes that scientific theories develop through variation and selection; Memetics is a theory of the variation, transmission, and selection of cultural items, such as ideas, fashions, and traditions; Dual inheritance theory a framework for cultural evolution developed largely independently of memetics
Eukaryogenesis, the process which created the eukaryotic cell and lineage, is a milestone in the evolution of life, since eukaryotes include all complex cells and almost all multicellular organisms. The process is widely agreed to have involved symbiogenesis , in which an archeon and a bacterium came together to create the first eukaryotic ...
It is a theory of biological evolution that seeks to explain aspects of organisms' anatomy and behavior by reference to the way that their life histories—including their reproductive development and behaviors, post-reproductive behaviors, and lifespan (length of time alive)—have been shaped by natural selection.
A scenario is a set of related concepts pertinent to the origin of life (abiogenesis), such as the iron-sulfur world.Many alternative abiogenesis scenarios have been proposed by scientists in a variety of fields from the 1950s onwards in an attempt to explain how the complex mechanisms of life could have come into existence.