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For example, organic chemistry has very few analogies with silicon chemistry, while silicate minerals have a structural complexity unseen in oxocarbons. [66] Silicon tends to resemble germanium far more than it does carbon, and this resemblance is enhanced by the d-block contraction , resulting in the size of the germanium atom being much ...
Silicon compounds are compounds containing the element silicon (Si). As a carbon group element, silicon often forms compounds in the +4 oxidation state, though many unusual compounds have been discovered that differ from expectations based on its valence electrons, including the silicides and some silanes. Metal silicides, silicon halides, and ...
Unconfirmed reports exist for nonequilibrium Si 2 O, Si 3 O 2, Si 3 O 4, Si 2 O 3 and Si 3 O 5. [94] Silicon sulfide is also a chain compound. Cyclic SiS 2 has been reported to exist in the gas phase. [95] The phase diagram of silicon with selenium has two phases: SiSe 2 and SiSe. [96] Tellurium silicide is a semiconductor with formula TeSi 2 ...
Silicon forms several hydrides; two of them are SiH 4 and Si 2 H 6. Silicon forms tetrahalides with fluorine (SiF 4), chlorine (SiCl 4), bromine (SiBr 4), and iodine (SiI 4). Silicon also forms a dioxide and a disulfide. [5] Silicon nitride has the formula Si 3 N 4. [6] Germanium forms five hydrides. The first two germanium hydrides are GeH 4 ...
Crystalline silicon has a metallic luster and a grayish color. Single crystals can be grown with the Czochralski process. Crystalline silicon can be doped with elements such as boron, gallium, germanium, phosphorus or arsenic. Doped silicon is used in solid-state electronic devices, such as solar cells, rectifiers and computer chips. [1]
A silicon–oxygen bond (Si−O bond) is a chemical bond between silicon and oxygen atoms that can be found in many inorganic and organic compounds. [1] In a silicon–oxygen bond, electrons are shared unequally between the two atoms , with oxygen taking the larger share due to its greater electronegativity .
However the chain of silicon atoms may also be branched at one or more silicon atoms. The number of possible isomers increases rapidly with the number of silicon atoms. The members of the series (in terms of number of silicon atoms) follow: silane, SiH 4, 1 silicon atom and 4 hydrogen atoms, analogous to methane
Thus, on both descending a period and crossing a group by one element, the changes "cancel" each other out, and elements with similar properties which have similar chemistry are often found – the atomic radius, electronegativity, properties of compounds (and so forth) of the diagonal members are similar.