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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
A cubic equation with real coefficients can be solved geometrically using compass, straightedge, and an angle trisector if and only if it has three real roots. [30]: Thm. 1 A cubic equation can be solved by compass-and-straightedge construction (without trisector) if and only if it has a rational root.
The cubic-plus-chain (CPC) [28] [29] [30] equation of state hybridizes the classical cubic equation of state with the SAFT chain term. [21] [22] The addition of the chain term allows the model to be capable of capturing the physics of both short-chain and long-chain non-associating components ranging from alkanes to polymers. The CPC monomer ...
Hence, all cubic equations of state can be considered 'modified van der Waals equation of state'. There is a very large number of such cubic equations of state. For process engineering, cubic equations of state are today still highly relevant, e.g. the Peng Robinson equation of state or the Soave Redlich Kwong equation of state.
The three-term virial equation or a cubic virial equation of state = + + has the simplicity of the Van der Waals equation of state without its singularity at v = b. Theoretically, the second virial coefficient represents bimolecular attraction forces, and the third virial term represents the repulsive forces among three molecules in close contact.
is pressure, temperature, volume, entropy, coefficient of thermal expansion, compressibility, heat capacity at constant volume, heat capacity at constant pressure. Maxwell's relations are a set of equations in thermodynamics which are derivable from the symmetry of second derivatives and from the definitions of the thermodynamic potentials .
In thermal physics and thermodynamics, the heat capacity ratio, also known as the adiabatic index, the ratio of specific heats, or Laplace's coefficient, is the ratio of the heat capacity at constant pressure (C P) to heat capacity at constant volume (C V).
The derivative of a cubic function is a quadratic function. A cubic function with real coefficients has either one or three real roots (which may not be distinct); [1] all odd-degree polynomials with real coefficients have at least one real root. The graph of a cubic function always has a single inflection point.