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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
A review by Berthod [19] studied the combined theories presented above and applied the Knox equation to independently determine the cause of the reduced efficiency. The Knox equation is commonly used in HPLC to describe the different contributions to overall band broadening of a solute. The Knox equation is expressed as: h = An^(1/3)+ B/n + Cn ...
A modern self-contained HPLC Schematic representation of an HPLC unit (1) solvent reservoirs, (2) solvent degasser, (3) gradient valve, (4) mixing vessel for delivery of the mobile phase, (5) high-pressure pump, (6) switching valve in "inject position", (6') switching valve in "load position", (7) sample injection loop, (8) pre-column (guard column), (9) analytical column, (10) detector (i.e ...
Schwarzschild and Fokker considered the advanced field of a system of moving charges, and the retarded field of a system of charges having the same geometry and opposite charges. Linearity of Maxwell's equations in vacuum allows one to add both systems, so that the charges disappear: This trick allows Maxwell's equations to become linear in matter.
In fluid dynamics, the Buckley–Leverett equation is a conservation equation used to model two-phase flow in porous media. [1] The Buckley–Leverett equation or the Buckley–Leverett displacement describes an immiscible displacement process, such as the displacement of oil by water, in a one-dimensional or quasi-one-dimensional reservoir.
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.
In mathematics, the Navier–Stokes equations are a system of nonlinear partial differential equations for abstract vector fields of any size. In physics and engineering, they are a system of equations that model the motion of liquids or non-rarefied gases (in which the mean free path is short enough so that it can be thought of as a continuum mean instead of a collection of particles) using ...
A schematic diagram of the Blasius flow profile. The streamwise velocity component () / is shown, as a function of the similarity variable .. Using scaling arguments, Ludwig Prandtl [1] argued that about half of the terms in the Navier-Stokes equations are negligible in boundary layer flows (except in a small region near the leading edge of the plate).