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J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
As dye-sublimation page printers utilize heat to transfer the dye onto the print media, the printing speed is limited by the speed at which the elements on the thermal head can change temperature. Heating the elements is easy, as a strong electric current can raise the temperature of an element very quickly.
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
Thermal-transfer printing is done by melting wax within the print heads of a specialized printer. The thermal-transfer print process utilises three main components: a non-movable print head, a carbon ribbon (the ink) and a substrate to be printed, which would typically be paper, synthetics, card or textile materials.
The form of the cooled surface often is a so-called cold finger which for very low-temperature sublimation may actually be cryogenically cooled. If the operation is a batch process , then the sublimed material can be collected from the cooled surface once heating ceases and the vacuum is released.
Cold finger used in sublimation.The raw product (6) is in the bottom of the outer tube (4) which is heated (7) while under vacuum (through side-arm 3). The sublimated material collects (5) on the cold finger proper, cooled by a coolant (blue) circulated through ports 1 and 2.
Solid carbon dioxide sublimes rapidly along the solid-gas boundary (sublimation point) below the triple point (e.g., at the temperature of −78.5 °C, at atmospheric pressure), whereas its melting into liquid CO 2 can occur along the solid-liquid boundary (melting point) at pressures and temperatures above the triple point (i.e., 5.1 atm, − ...
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