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The history of thermodynamics is a fundamental strand in the history of physics, the history of chemistry, and the history of science in general. Due to the relevance of thermodynamics in much of science and technology, its history is finely woven with the developments of classical mechanics, quantum mechanics, magnetism, and chemical kinetics, to more distant applied fields such as ...
The schools with the most-lasting influence on the modern versions of thermodynamics are the Berlin school, particularly Rudolf Clausius's 1865 textbook The Mechanical Theory of Heat, the Vienna school, with the statistical mechanics of Ludwig Boltzmann, and the Gibbsian school at Yale University of Willard Gibbs' 1876 and his book On the ...
An equivalent statement of the Dulong–Petit law in modern terms is that, regardless of the nature of the substance, the specific heat capacity c of a solid element (measured in joule per kelvin per kilogram) is equal to 3R/M, where R is the gas constant (measured in joule per kelvin per mole) and M is the molar mass (measured in kilogram per mole).
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...
1865 – Clausius introduces the modern macroscopic concept of entropy; 1865 – Josef Loschmidt applies Maxwell's theory to estimate the number-density of molecules in gases, given observed gas viscosities. 1867 – Maxwell asks whether Maxwell's demon could reverse irreversible processes; 1870 – Clausius proves the scalar virial theorem
Relativistic heat conduction refers to the modelling of heat conduction (and similar diffusion processes) in a way compatible with special relativity. In special (and general ) relativity, the usual heat equation for non-relativistic heat conduction must be modified, as it leads to faster-than-light signal propagation.
Conduction heat flux q k for ideal gas is derived with the gas kinetic theory or the Boltzmann transport equations, and the thermal conductivity is =, -, where u f 2 1/2 is the RMS (root mean square) thermal velocity (3k B T/m from the MB distribution function, m: atomic mass) and τ f-f is the relaxation time (or intercollision time period ...
Thermal physics, generally speaking, is the study of the statistical nature of physical systems from an energetic perspective. Starting with the basics of heat and temperature, thermal physics analyzes the first law of thermodynamics and second law of thermodynamics from the statistical perspective, in terms of the number of microstates corresponding to a given macrostate.