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For many substances, the formation reaction may be considered as the sum of a number of simpler reactions, either real or fictitious. The enthalpy of reaction can then be analyzed by applying Hess' law, which states that the sum of the enthalpy changes for a number of individual reaction steps equals the enthalpy change of the overall reaction.
Enthalpy of transformation. This applies to the transformations from one solid phase to another, such as the transformation from α-Fe (bcc ferrite) to -Fe (fcc austenite). The transformation is designated ΔH tr. Enthalpy of fusion or melting. This applies to the transition of a solid to a liquid and is designated ΔH m.
26 Fe iron (alpha) use: ... Section 6, Thermodynamic Properties; Table 6.3, Enthalpies and Gibbs Energies of Formation, Entropies, and Heat Capacities of the ...
Miedema's model is a semi-empirical approach for estimating the heat of formation of solid or liquid ... This Table, reports the three ... Fe 0 0 0 0 0 0 0 0 0 0 ...
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
The enthalpy of formation of one mole of ethane gas refers to the reaction 2 C (graphite) + 3 H 2 (g) → C 2 H 6 (g). Standard enthalpy of hydrogenation is defined as the enthalpy change observed when one mole of an unsaturated compound reacts with an excess of hydrogen to become fully saturated.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe 3 C. By weight, it is 6.67% carbon and 93.3% iron.