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TMS is a contaminant in the atmospheres of spacecraft, where it arises from the degradation of silicone-based materials. [5] Specifically, it is the volatile product from the hydrolysis of polydimethylsiloxane, which are generally terminated with trimethylsilyl groups:
Polydimethylsiloxane (PDMS), also known as dimethylpolysiloxane or dimethicone, is a silicone polymer with a wide variety of uses, from cosmetics to industrial lubrication and passive daytime radiative cooling. [1] [2] [3] PDMS is particularly known for its unusual rheological (or flow) properties.
Polydimethylsiloxane is a prevalent siloxane. In organosilicon chemistry, a siloxane is an organic compound containing a functional group of two silicon atoms bound to an oxygen atom: Si−O−Si. The parent siloxanes include the oligomeric and polymeric hydrides with the formulae H[OSiH 2] n OH and [OSiH 2] n. [1]
The original coral-colored Silly Putty is composed of 65% dimethylsiloxane (hydroxy-terminated polymers with boric acid), 17% silica (crystalline quartz), 9% Thixatrol ST (castor oil derivative), 4% polydimethylsiloxane, 1% decamethyl cyclopentasiloxane, 1% glycerine, and 1% titanium dioxide. [6] Silly Putty flowing through a hole
One person was killed after an enormous fire Monday night at a suburban Detroit warehouse, known to stock combustible materials, ignited explosions, shook homes and rained down debris as far as a ...
Polymethylhydrosiloxane (PMHS) is a polymer with the general structure [−CH 3 (H)Si−O−].It is used in organic chemistry as a mild and stable reducing agent easily transferring hydrides to metal centers and a number of other reducible functional groups.
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The termination steps of free radical polymerization steps are of two types: recombination and disproportionation. [2] In a recombination step, two growing chain radicals (denoted by •) form a covalent bond in a single stable molecule. For the example of a vinyl polymer,