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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
The so-called β-Al 2 O 3 proved to be NaAl 11 O 17. [18] Molten aluminium oxide near the melting temperature is roughly 2/3 tetrahedral (i.e. 2/3 of the Al are surrounded by 4 oxygen neighbors), and 1/3 5-coordinated, with very little (<5%) octahedral Al-O present. [19]
The AKF diagram is intended for rocks containing excess aluminium and silica. Its components are: A = Al 2 O 3 - (CaO + Na 2 O + K 2 O) K = K 2 O F = FeO + MgO + MnO. This diagram is less useful, because magnesium does not freely substitute for ferrous iron in many metamorphic minerals important in aluminium-rich rock.
In reduction, Al 2 O is a major component of vapors of Al 2 O 3. There are also 12 valence electrons in Al 2 O. [3] Al 2 O molecules can be detected by mass spectrometry, infrared emission, and ultraviolet absorption and emission in the gas phase. The molecule is linear at equilibrium in the ground state. [4]
CuCl 2 reacts with HCl or other chloride sources to form complex ions: the red [CuCl 3] − (found in potassium trichloridocuprate(II) K[CuCl 3]) (it is a dimer in reality, [Cu 2 Cl 6] 2−, a couple of tetrahedrons that share an edge), and the green or yellow [CuCl 4] 2− (found in potassium tetrachloridocuprate(II) K 2 [CuCl 4]).
[2] KCuO 2 was discovered first in 1952 by V. K. Wahl and W. Klemm, they synthesized this compound by heating copper(II) oxide and potassium superoxide in an atmosphere of oxygen. [3] 2 KO 2 + 2 CuO → 2 KCuO 2 + O 2. It can also be synthesized by heating potassium superoxide and copper powder: [4] KO 2 + Cu → KCuO 2. KCuO 2 reacts with the ...
BF 3 + OMe 2 → BF 3 OMe 2. Both BF 4 − and BF 3 OMe 2 are Lewis base adducts of boron trifluoride. Many adducts violate the octet rule, such as the triiodide anion: I 2 + I − → I − 3. The variability of the colors of iodine solutions reflects the variable abilities of the solvent to form adducts with the Lewis acid I 2.
6 O 18− 18 anion, found in tricalcium aluminate, Ca 3 Al 2 O 6, which can be considered to consist of 6 corner sharing {AlO 4} tetrahedra. [5] A number of infinite chain anions in the compounds Na 7 Al 3 O 8 which contains rings linked to form chains, Na 7 Al 13 O 10 and Na 17 Al 5 O 16 which contain discrete chain anions. [6]