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Toluene diisocyanate (TDI) is an organic compound with the formula CH 3 C 6 H 3 (NCO) 2.Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively.
The global market for diisocyanates in the year 2000 was 4.4 million tonnes, of which 61.3% was methylene diphenyl diisocyanate (MDI), 34.1% was toluene diisocyanate (TDI), 3.4% was the total for hexamethylene diisocyanate (HDI) and isophorone diisocyanate (IPDI), and 1.2% was the total for various others. [18]
It is mainly used to manufacture toluene diisocyanate, which is a key raw material in polyurethane chemistry. [4] It is still the starting material used when non-phosgene methods of production of toluene diisocyanate are used. [5] [6] It is also a degradation product of polyurethane materials produced using toluene diisocyanate.
Hazard statements. H302, H312, H315, ... Toluene diisocyanate: Except where otherwise noted, data are given for materials in their standard state (at 25 °C ...
Hippuric acid has long been used as an indicator of toluene exposure; [14] however, there appears to be some doubt about its validity. [15] There is significant endogenous hippuric acid production by humans; which shows inter- and intra-individual variation influenced by factors such as diet, medical treatment, alcohol consumption, etc. [15] This suggests that hippuric acid may be an ...
The IARC Monographs on which this list is based assess the hazard linked to the ... 3,3'-Dimethoxybenzidine-4,4'-diisocyanate; ... Vinyl toluene; Vitamin K substances;
This is the list of extremely hazardous substances defined in Section 302 of the U.S. Emergency Planning and Community Right-to-Know Act (42 U.S.C. § 11002).The list can be found as an appendix to 40 CFR 355. [1]
Most DNT is used in the production of toluene diisocyanate, which is used to produce flexible polyurethane foams. DNT is hydrogenated to produce 2,4-toluenediamine, which in turn is phosgenated to give toluene diisocyanate. In this way, about 1.4 billion kilograms are produced annually, as of the years 1999–2000. [6]