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[6]: 2 Methane is a major source of water vapour in the stratosphere through oxidation; [7] and water vapour adds about 15% to methane's radiative forcing effect. [8] The global warming potential (GWP) for methane is about 84 in terms of its impact over a 20-year timeframe, and 28 in terms of its impact over a 100-year timeframe.
Hydrogen, being the lightest existing gas (7% the density of air, 0.08988 g/L at STP), seems to be the most appropriate gas for lifting.It can be easily produced in large quantities, for example with the water-gas shift reaction or electrolysis, but hydrogen has several disadvantages:
Hydrogen can be purified by passing through a membrane composed of palladium and silver. Permeability of the former to hydrogen was discovered back in the 1860s. [2] An alloy with a ca. 3:1 ratio for Pd:Ag is more structural robust than pure Pd, which is the active component that allows the selective diffusion of H 2 through it.
Methane is easier to store than hydrogen due to its higher boiling point and density, as well as its lack of hydrogen embrittlement. [31] [32] The lower molecular weight of the exhaust also increases the fraction of the heat energy which is in the form of kinetic energy available for propulsion, increasing the specific impulse of the rocket.
Methane has a limited atmospheric lifetime, about 10 years, due to substantial methane sinks. The primary methane sink is atmospheric oxidation, from hydroxyl radicals (~90% of the total sink) and chlorine radicals (0-5% of the total sink). The rest is consumed by methanotrophs and other methane-oxidizing bacteria and archaea in soils (~5%). [7]
Separation of hydrogen from gases like nitrogen and methane; Recovery of hydrogen from product streams of ammonia plants; Recovery of hydrogen in oil refinery processes; Separation of methane from the other components of biogas; Enrichment of air by oxygen for medical or metallurgical purposes.
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