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In thermodynamics, the cryoscopic constant, Kf, relates molality to freezing point depression (which is a colligative property). It is the ratio of the latter to the former: b is the molality of the solution. Through cryoscopy, a known constant can be used to calculate an unknown molar mass. The term "cryoscopy" means "freezing measurement" in ...
Freezing point depression is responsible for keeping ice cream soft below 0°C. [1] Freezing-point depression is a drop in the maximum temperature at which a substance freezes, caused when a smaller amount of another, non- volatile substance is added. Examples include adding salt into water (used in ice cream makers and for de-icing roads ...
Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin. This is related to cryoscopy, which determines the same value from the cryoscopic constant (of freezing point depression). This property of elevation of boiling point is a ...
List of boiling and freezing information of solvents. Solvent. Density (g cm-3) Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source. Aniline.
Boiling-point elevation. Boiling-point elevation is the phenomenon whereby the boiling point of a liquid (a solvent) will be higher when another compound is added, meaning that a solution has a higher boiling point than a pure solvent. This happens whenever a non-volatile solute, such as a salt, is added to a pure solvent, such as water.
The temperature and pressure at which ordinary solid, liquid, and gaseous water coexist in equilibrium is a triple point of water. Since 1954, this point had been used to define the base unit of temperature, the kelvin, [45] [46] but, starting in 2019, the kelvin is now defined using the Boltzmann constant, rather than the triple point of water ...
Colligative properties. In chemistry, colligative properties are those properties of solutions that depend on the ratio of the number of solute particles to the number of solvent particles in a solution, and not on the nature of the chemical species present. [1] The number ratio can be related to the various units for concentration of a ...
The freezing point of a solution is lower than that of the pure solvent, and the freezing-point depression (ΔT) is directly proportional to the amount concentration for dilute solutions. When the composition is expressed as a molality , the proportionality constant is known as the cryoscopic constant ( K f ) and is characteristic for each solvent.