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  2. Pyrophoricity - Wikipedia

    en.wikipedia.org/wiki/Pyrophoricity

    The creation of sparks from metals is based on the pyrophoricity of small metal particles, and pyrophoric alloys are made for this purpose. [2] Practical applications include the sparking mechanisms in lighters and various toys, using ferrocerium; starting fires without matches, using a firesteel; the flintlock mechanism in firearms; and spark testing ferrous metals.

  3. Water-reactive substances - Wikipedia

    en.wikipedia.org/wiki/Water-reactive_substances

    Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .

  4. Silane - Wikipedia

    en.wikipedia.org/wiki/Silane

    Silane (Silicane) is an inorganic compound with chemical formula SiH 4. It is a colorless, pyrophoric gas with a sharp, repulsive, pungent smell, somewhat similar to that of acetic acid. [6] Silane is of practical interest as a precursor to elemental silicon.

  5. Diisopropylzinc - Wikipedia

    en.wikipedia.org/wiki/Diisopropylzinc

    Diisopropylzinc is an organozinc compound with the chemical formula ZnC 6 H 14. [1] It is the key reagent in the Soai reaction, which is both autocatalytic and enantiospecific. [2] This chemical is pyrophoric, bursting into flame in air or in contact with water. It is generally packaged in toluene. [3]

  6. Trimethylaluminium - Wikipedia

    en.wikipedia.org/wiki/Trimethylaluminium

    In combination with 20 to 100 mol % Cp 2 ZrCl 2 (zirconocene dichloride), the (CH 3) 2 Al-CH 3 adds "across" alkynes to give vinyl aluminium species that are useful in organic synthesis in a reaction known as carboalumination.

  7. Triethylborane - Wikipedia

    en.wikipedia.org/wiki/Triethylborane

    After reaction with methyl iodide the former mixture gives 2,2-dimethylcyclohexanone in 90% yield while the latter produces 2,6-dimethylcyclohexanone in 93% yield. [7] [8] The Et stands for ethyl group CH 3 CH 2 −. It is used in the Barton–McCombie deoxygenation reaction for deoxygenation of alcohols.

  8. Raney nickel - Wikipedia

    en.wikipedia.org/wiki/Raney_nickel

    Due to its large surface area and high volume of contained hydrogen gas, dry, activated Raney nickel is a pyrophoric material that requires handling under an inert atmosphere. Raney nickel is typically supplied as a 50% slurry in water. Even after reaction, residual Raney nickel contains significant amounts of hydrogen gas and may spontaneously ...

  9. Trimethylgallium - Wikipedia

    en.wikipedia.org/wiki/Trimethylgallium

    It is a colorless, pyrophoric liquid. [1] Unlike trimethylaluminium , TMG adopts a monomeric structure. [ 2 ] When examined in detail, the monomeric units are clearly linked by multiple weak Ga---C interactions, reminiscent of the situation for trimethylindium .

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