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Heat traps are valves or loops of pipe on the cold water inlet and hot water outlet of water heaters. The heat traps allow cold water to flow into the water heater tank, but prevent unwanted natural convection and heated water to flow out of the tank. [1] [2] Newer water heaters have built-in heat traps.
The actual attack on the metal is by the corrosive action of the water to which it is exposed while the erosive factor is the mechanical removal of the corrosion product from the surface. Impingement attack produces highly characteristic water-swept pits, which are often horseshoe shaped, or it can produce broader areas of attack.
Another example is the cathodic protection of buried or submerged structures as well as hot water storage tanks. In this case, sacrificial anodes work as part of a galvanic couple, promoting corrosion of the anode, while protecting the cathode metal.
Over time the galvanic anode continues to corrode, consuming the anode material until eventually it must be replaced. Galvanic or sacrificial anodes are made in various shapes and sizes using alloys of zinc, magnesium, and aluminum. ASTM International publishes standards on the composition and manufacturing of galvanic anodes. [10] [11] [12]
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]
In addition to being cold hard and organically pure, the water needs a specific chemistry. The effect of the water chemistry can be empirically determined though use of the Pitting Propensity Rating (PPR) a number that takes into account the sulfate, chloride, nitrate and sodium ion concentrations of the water as well as its acidity or pH. A ...
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