Search results
Results from the WOW.Com Content Network
Hydrogen ions travel through the electrolyte. They react at the cathode with oxygen from the air and the electrons from the external circuit forming water. Bio-Ethanol based fuel cells may improve the well-to-wheel balance of this biofuel because of the increased conversion rate of the fuel cell compared to the internal combustion engine.
Finally, pyruvate is converted to ethanol and CO 2 in two steps, regenerating oxidized NAD+ needed for glycolysis: 1. CH 3 COCOO − + H + → CH 3 CHO + CO 2. catalyzed by pyruvate decarboxylase. 2. CH 3 CHO + NADH + H + → C 2 H 5 OH + NAD + This reaction is catalyzed by alcohol dehydrogenase (ADH1 in baker's yeast). [3]
Alcohol aminations are among the most commonly utilized borrowing hydrogen processes. [13] [14] [15] In reactions of this type, alcohol dehydrogenation is followed by reductive amination of the resulting carbonyl compound. This represents an alternative to two-step processes involving conversion of the alcohol to a halide or sulfonate ester ...
Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula CH 3 CH 2 OH. It is an alcohol, with its formula also written as C 2 H 5 OH, C 2 H 6 O or EtOH, where Et stands for ethyl. Ethanol is a volatile, flammable, colorless liquid with a characteristic wine-like ...
The total amount of energy input into the process compared to the energy released by burning the resulting ethanol fuel is known as the energy balance (or "energy returned on energy invested"). Figures compiled in a 2007 report by National Geographic [ 68 ] point to modest results for corn ethanol produced in the US: one unit of fossil-fuel ...
If the reaction stops part way through the metabolic pathways, which happens because acetic acid is excreted in the urine after drinking, then not nearly as much energy can be derived from alcohol, indeed, only 215.1 kJ/mol. At the very least, the theoretical limits on energy yield are determined to be −215.1 kJ/mol to −1 325.6 kJ/mol.
In other words, for the same energy content as one liter or one gallon of gasoline, one needs 1.6 liters/gallons of ethanol and 2.1 liters/gallons of methanol. The raw energy-per-volume numbers produce misleading fuel consumption numbers, however, because alcohol-fueled engines can be made substantially more energy-efficient.
If the alcohol produced by the reaction can be separated from the reactants by distillation this will drive the equilibrium toward the products. This means that esters with larger alkoxy groups can be made from methyl or ethyl esters in high purity by heating the mixture of ester, acid/base, and large alcohol.