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Complexes of vanadium(II) and (III) are relatively exchange inert and reducing. Those of V(IV) and V(V) are oxidants. Vanadium ion is rather large and some complexes achieve coordination numbers greater than 6, as is the case in [V(CN) 7] 4−. Oxovanadium(V) also forms 7 coordinate coordination complexes with tetradentate ligands and peroxides ...
Vanadium(II) compounds are reducing agents, and vanadium(V) compounds are oxidizing agents. Vanadium(IV) compounds often exist as vanadyl derivatives, which contain the VO 2+ center. [23] Ammonium vanadate(V) (NH 4 VO 3) can be successively reduced with elemental zinc to obtain the different colors of vanadium in these four oxidation states.
Vanadium(II) chloride – VCl 2; Vanadium(III) ... Sodium hydrogen carbonate (Sodium bicarbonate) – NaHCO 3; Sodium hydrosulfide – NaSH; Sodium hydroxide – NaOH;
The bicarbonate ion (hydrogencarbonate ion) is an anion with the empirical formula HCO − 3 and a molecular mass of 61.01 daltons; it consists of one central carbon atom surrounded by three oxygen atoms in a trigonal planar arrangement, with a hydrogen atom attached to one of the oxygens.
The complex is generally prepared from vanadium(IV), e.g. vanadyl sulfate: [1] VOSO 4 + 2 Hacac → VO(acac) 2 + H 2 SO 4. It can also be prepared by a redox reaction starting with vanadium pentoxide. In this reaction, some acetylacetone is oxidized to 2,3,4-Pentanetrione. [1]
The anion exchanger family (TC# 2.A.31, also named bicarbonate transporter family) is a member of the large APC superfamily of secondary carriers. [1] Members of the AE family are generally responsible for the transport of anions across cellular barriers, although their functions may vary. All of them exchange bicarbonate. Characterized protein ...
This hygroscopic blue solid is one of the most common sources of vanadium in the laboratory, reflecting its high stability. It features the vanadyl ion, VO 2+, which has been called the "most stable diatomic ion". [1] Vanadyl sulfate is an intermediate in the extraction of vanadium from petroleum residues, one commercial source of vanadium. [2]
Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t 2g orbitals.