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A homologue (also spelled as homolog) is a compound belonging to a homologous series. [1] Compounds within a homologous series typically have a fixed set of functional groups that gives them similar chemical and physical properties. (For example, the series of primary straight-chained alcohols has a hydroxyl at the end of the carbon chain ...
In organic chemistry, a homologation reaction, also known as homologization, is any chemical reaction that converts the reactant into the next member of the homologous series. A homologous series is a group of compounds that differ by a constant unit, generally a methylene (−CH 2 −) group.
Homologous sequences are paralogous if they were created by a duplication event within the genome. For gene duplication events, if a gene in an organism is duplicated, the two copies are paralogous. They can shape the structure of whole genomes and thus explain genome evolution to a large extent. Examples include the Homeobox genes in animals.
Homologous series, a series of organic compounds having different quantities of a repeated unit; Homologous temperature, the temperature of a material as a fraction of its absolute melting point; Homologation reaction, a chemical reaction which produces the next logical member of a homologous series
Alkyl groups form homologous series. The simplest series have the general formula −C n H 2n+1. Alkyls include methyl, (−CH 3), ethyl (−C 2 H 5), propyl (−C 3 H 7), butyl (−C 4 H 9), pentyl (−C 5 H 11), and so on. Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl.
As a rule of thumb, the boiling point rises 20–30 °C for each carbon added to the chain; this rule applies to other homologous series. [18] A straight-chain alkane will have a boiling point higher than a branched-chain alkane due to the greater surface area in contact, and thus greater van der Waals forces, between adjacent molecules.
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The example above is an example alloparalogy. Symparalogs are paralogs that evolved from gene duplication of paralogous genes in subsequent speciation events. From the example above, if the descendant with genes A1 and B underwent another speciation event where gene A1 duplicated, the new species would have genes B, A1a, and A1b.