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If the concentration of a reactant remains constant (because it is a catalyst, or because it is in great excess with respect to the other reactants), its concentration can be included in the rate constant, leading to a pseudo–first-order (or occasionally pseudo–second-order) rate equation. For a typical second-order reaction with rate ...
For example, the second-order equation y′′ = −y can be rewritten as two first-order equations: y′ = z and z′ = −y. In this section, we describe numerical methods for IVPs, and remark that boundary value problems (BVPs) require a different set of tools. In a BVP, one defines values, or components of the solution y at more than one ...
See Template:Date table sorting for more info. In the tables below, all columns sort correctly. The wikitext for the first entry in each table in the first row is shown in the table header. Note: None of the table columns use the data-sort-type= modifier. Using data-sort-type= can sometimes break sorting when used with the template.
In chemistry, the effective molarity (denoted EM) [1] is defined as the ratio between the first-order rate constant of an intramolecular reaction and the second-order rate constant of the corresponding intermolecular reaction (kinetic effective molarity) [1] [2] or the ratio between the equilibrium constant of an intramolecular reaction and the equilibrium constant of the corresponding ...
The classical Pade scheme for the first derivative at a cell with index (′) reads; ′ + ′ + + ′ = +. Where is the spacing between points with index , & +.The equation yields a fourth-order accurate solution for ′ when supplemented with suitable boundary conditions (typically periodic).
Template:Table alignment (see previous section) will not work on columns of row headers. There are some other limitations listed at Template:Table alignment. In these cases you can try the following method for the first column only. This can be done in the wikitext source editor.
You can add a table using HTML rather than wiki markup, as described at HTML element#Tables. However, HTML tables are discouraged because wikitables are easier to customize and maintain, as described at manual of style on tables. Also, note that the <thead>, <tbody>, <tfoot>, <colgroup>, and <col> elements are not supported in wikitext.
First-order approximation is the term scientists use for a slightly better answer. [3] Some simplifying assumptions are made, and when a number is needed, an answer with only one significant figure is often given ("the town has 4 × 10 3, or four thousand, residents"). In the case of a first-order approximation, at least one number given is exact.