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4-Methylpyridine is the organic compound with the formula CH 3 C 5 H 4 N. It is one of the three isomers of methylpyridine. This pungent liquid is a building block for the synthesis of other heterocyclic compounds. Its conjugate acid, the 4-methylpyridinium ion, has a pK a of 5.98, about 0.7 units above that of pyridine itself. [1]
Anderson also named picoline by combining the Latin words pix (tar) and oleum (oil) because coal tar oil was a source of picoline. [ 4 ] [ 5 ] By 1870, the German chemist Adolf von Baeyer had synthesized picoline in two ways: by the dry distillation of acroleïnammoniak (CH 2 =CH-CH=N-CHOH-CH=CH 2 ) [ 6 ] and by heating tribromallyl ( 1,2,3 ...
2-Methylpyridine, or 2-picoline, is the compound described with formula C 6 H 7 N. 2-Picoline is a colorless liquid that has an unpleasant odor similar to pyridine. It is mainly used to make vinylpyridine and the agrichemical nitrapyrin .
3-Methylpyridine or 3-picoline, is an organic compound with formula 3-CH 3 C 5 H 4 N. It is one of three positional isomers of methylpyridine, whose structures vary according to where the methyl group is attached around the pyridine ring. This colorless liquid is a precursor to pyridine derivatives that have applications in the pharmaceutical ...
On a commercial scale, picolinic acid is produced by ammoxidation of 2-picoline followed by hydrolysis of the resulting nitrile: NC 5 H 4 CH 3 + 1.5 O 2 + NH 3 → NC 5 H 4 C≡N + 3 H 2 O NC 5 H 4 C≡N + 2 H 2 O → NC 5 H 4 CO 2 H + NH 3. It is also produced by oxidation of picoline with nitric acid. [2]
Nicotinonitrile or 3-cyanopyridine is an organic compound with the formula NCC 5 H 4 N. The molecule consists of a pyridine ring with a nitrile group attached to the 3-position. A colorless solid, it is produced by ammoxidation of 3-methylpyridine: [2] H 3 CC 5 H 4 N + NH 3 + 1.5 O 2 → NCC 5 H 4 N + 3 H 2 O. Nicotinonitrile is a precursor to ...
Pyridine-2-carbaldehyde, also called 2-formylpyridine, is an organic compound with the formula NC 5 H 4 CHO. It is one of three isomeric pyridinaldehydes. The other isomers are pyridine-3-carboxaldehyde and pyridine-4-carboxaldehyde. Pyridine-2-carbaldehyde is a colorless oily liquid with a distinctive odor.
5-Ethyl-2-methylpyridine is produced by condensation of paraldehyde (a derivative of acetaldehyde) and ammonia: [2]. 4 CH 3 CHO + NH 3 → (C 2 H 5)(CH 3)C 5 H 3 N + 4 H 2 O. The conversion is an example of a structurally complex compound efficiently made from simple precursors.