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2,6-Di-tert-butylpyridine, a weak non-nucleophilic base [2] pK a = 3.58 Phosphazene bases , such as t -Bu-P 4 [ 3 ] Non-nucleophilic bases of high strength are usually anions.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
Another structural difference is the sliding back mechanism (sometimes called wall hugger or wall climber) which allows to minimise the gap with the back wall when the bed is uplifted, keeps the bedside table within reach, and enables the partners using the bed (if split) to keep eye contact at all times. In the 90's the sliding back mechanism ...
There are many varieties of beds: An adjustable bed is a bed that can be adjusted to a number of different positions. Most hospital beds are adjustable, so that a patient can have different parts of their body elevated for medical reasons. Some people have adjustable beds in private homes.
According to IUPAC neo is only recommended in neopentane or the neopentyl residue. [23] [24] cyclo is a frequently used prefix for all cyclic and heterocyclic compounds. In many proper names of chemical substances cyclo is not used as a prefix but directly part of the name, for example in cyclohexane or cyclooctatetraene.
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tert-Butyloxycarbonyl protecting group. The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group [1] (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can be added to amines under aqueous conditions using di-tert-butyl dicarbonate in the presence of a base such as sodium hydroxide:
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