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Buffer capacity falls to 33% of the maximum value at pH = pK a ± 1, to 10% at pH = pK a ± 1.5 and to 1% at pH = pK a ± 2. For this reason the most useful range is approximately pK a ± 1. When choosing a buffer for use at a specific pH, it should have a pK a value as close as possible to that pH. [2]
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Water retention curve is the relationship between the water content, θ, and the soil water potential, ψ. The soil moisture curve is characteristic for different types of soil, and is also called the soil moisture characteristic. It is used to predict the soil water storage, water supply to the plants (field capacity) and soil aggregate stability.
Moisture equivalent is proposed by Lyman Briggs and McLane (1910) as a measure of field capacity for fine-textured soil materials. Moisture equivalent is defined as the percentage of water which a soil can retain in opposition to a centrifugal force 1000 times that of gravity. It is measured by saturating sample of soil 1 cm thick, and ...
Soil mineral components belonging to a given textural class may thus share properties linked to their specific surface area (e.g. moisture retention) but not those linked to their chemical composition (e.g. cation exchange capacity). Soil components larger than 2.0 mm (0.079 in) are classed as rock and gravel and are removed before determining ...
In geology, a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently, oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history.
Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. [1] Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. [ 2 ]
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